Stylish duo Jennifer Aniston and Justin Theroux complemented each other in black ensembles as they attended the star-studded Academy of Motion Picture Arts and Sciences’ Governors Award over the weekend.

Jennifer, 45, showed off her enviable figure in a Zuhair Murad bustier dress, which featured an elegant beaded bodice and floral-embroidered skirt.

CLICK FOR A GALLERY OF THE NIGHT’S BEST FASHIONJennifer Aniston and Justin Theroux look loved-up on the red carpet

The former Friends star accessorised her chic ensemble with a pair of black stilettos and a black and gold clutch bag, finishing off her look with a pair of dazzling statement earrings.

Staying true to her laidback style, Jennifer wore her hair in a sleek low ponytail, and kept her make-up to a minimum. The Just Go With It actress opted for a hint of peach blush on her cheeks and nude glossy lips, adding red carpet-worthy glamour with black eyeliner and fluttery eyelashes.

Fiancé Justin was all smiles as he posed, looking handsome in a black suit and tie combo, to complement Jennifer’s glamorous ensemble.

Jennifer and Justin were not the only couple making a stylish duo on the red carpet.

Emily Blunt and John Krasinski were all smiles at the awards ceremony

The Devil Wears Prada actress Emily Blunt was joined by husband John Krasinski on the red carpet, and the two shared a laugh as they posed for the cameras.

Emily, who gave birth to the couple’s first child in February, looked beautiful in a figure-hugging fuschia pink dress with colourful embellished detail and a mermaid-style skirt.

The 31-year-old chose to channel her gown’s bright colour into her beauty look with a shade of dark pink lipstick. She wore her hair slicked back into a chic bun, accessorising her outfit with a box clutch bag.