The 29-year-old songstress chose a Brian Rennie for Basler peplum gown for China’s biggest awards show, which featured optical-illusion black side panels that showed off her curvy figure.
With her wavy blond hair dramatically parted to one side, the pop-punk singer complemented the glamorous look with winged eyeliner and a nude lip.
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Nickelback frontman Chad colour-coordinated with his beautiful wife in a black tuxedo, crisp white shirt and black tie.
Avril, who won Best Global Singer at the colloquially named ‘Chinese Oscars,’ later changed outfits and posed backstage in a short-sleeved black dress -- complete with studded belt and fishnet stockings.
She added: "I look forward to you guys hearing my new music from my record next month, thank you very much, Xièxiè" (the Mandarin word for "thank you").
The Canadian power couple — who were wed in a romantic ceremony this past summer — are fans of coordinating their red carpet looks, most notably at the 2013 Much Music Video Awards, where they arrived together wearing all-black, rocker-inspired ensembles.
Avril Lavigne’s upcoming album is slated for release on Nov 5.